Engineering molecular aggregate spectra

Details Engineering molecular aggregate spectra Engineering molecular aggregate spectra

2008-09-16

arxiv.org/abs/0809.2753v1

phys. stat. sol. (c) 6, 224 (2009)

Physics

Condensed Matter

Materials Science

4 two-column pages, Proceedings of the 8th International Conference on Excitonic Processes in Condensed Matter, June 22-27, Ky

Scientific paper

10.1002/pssc.200879867

We show that optical properties of linear molecular aggregates undergo drastic changes when aggregates are deposited on a metal surface. The dipole-dipole interactions of monomers with their images can result in strong {re-structuring of both the exciton band and the absorption spectrum, depending on the arrangement of the monomer transition dipoles with respect to the surface.

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