Polymer translocation through a nanopore - a showcase of anomalous diffusion

Details Polymer translocation through a nanopore - a showcase of anomalous diffusion Polymer translocation through a nanopore - a showcase of anomalous diffusion

2007-01-26

arxiv.org/abs/cond-mat/0701664v2

Phys. Rev. E 76, 010801(R) (2007)

Physics

Condensed Matter

Soft Condensed Matter

5 pages, 3 figures, accepted for publication in Phys. Rev. E

Scientific paper

10.1103/PhysRevE.76.010801

The translocation dynamics of a polymer chain through a nanopore in the absence of an external driving force is analyzed by means of scaling arguments, fractional calculus, and computer simulations. The problem at hand is mapped on a one dimensional {\em anomalous} diffusion process in terms of reaction coordinate $s$ (i.e. the translocated number of segments at time $t$) and shown to be governed by an universal exponent $\alpha = 2/(2\nu+2-\gamma_1)$ whose value is nearly the same in two- and three-dimensions. The process is described by a {\em fractional} diffusion equation which is solved exactly in the interval $0 $, and $ - < s(t)>^2$ which provide full description of the diffusion process. The comparison of the analytic results with data derived from extensive Monte Carlo (MC) simulations reveals very good agreement and proves that the diffusion dynamics of unbiased translocation through a nanopore is anomalous in its nature.