Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2001-09-28
Phys. Rev. Lett. 87, 106101, (2001)
Physics
Condensed Matter
Soft Condensed Matter
3 .eps figures, 5pp
Scientific paper
10.1103/PhysRevLett.87.106101
Long-ranged electrostatic interactions in electrolytes modify their contact angles on charged substrates in a scale and geometry dependent manner. For angles measured at scales smaller than the typical Debye screening length, the wetting geometry near the contact line must be explicitly considered. Using variational and asymptotic methods, we derive new transcendental equations for the contact angle that depend on the electrostatic potential only at the three phase contact line. Analytic expressions are found in certain limits and compared with predictions for contact angles measured with lower resolution. An estimate for electrostatic contributions to {\it line} tension is also given.
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