Glass transitions and dynamics in thin polymer films: dielectric relaxation of thin films of polystyrene

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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13 pages, 11 figures, and 3 tables

Scientific paper

10.1103/PhysRevE.61.1743

The glass transition temperature $T_{\rm g}$ and the temperature $T_{\alpha}$ corresponding to the peak in the dielectric loss due to the $\alpha$-process have been simultaneously determined as functions of film thickness d through dielectric measurements for polystyrene thin films supported on glass substrate. The dielectric loss peaks have also been investigated as functions of frequency for a given temperature. A decrease in $T_{\rm g}$ was observed with decreasing film thickness, while $T_{\alpha}$ was found to remain almost constant for $d>d_{\rm c}$ and to decrease drastically with decreasing d for $d

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