Structural response to O*-O' and magnetic transitions in orthorhombic perovskites

Details Structural response to O*-O' and magnetic transitions in orthorhombic perovskites Structural response to O*-O' and magnetic transitions in orthorhombic perovskites

2002-06-11

arxiv.org/abs/cond-mat/0206181v1

Phys. Rev. B66, 224414 (2002)

Physics

Condensed Matter

Materials Science

13 pages, including 13 figures and 2 tables

Scientific paper

10.1103/PhysRevB.66.224414

We present a temperature dependent single crystal x-ray diffraction study of twinned orthorhombic perovskites La1-xCaxMnO3, for x=0.16 and x=0.25. These data show the evolution of the crystal structure from the ferromagnetic insulating state to the ferromagnetic metallic state. The data are modelled in space group Pnma with twin relations based on a distribution of the b axis over three perpendicular cubic axes. The twin model allows full structure determination in the presence of up to six twin fractions using the single crystal x-ray diffraction data.

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