Liesegang patterns: Effect of dissociation of the invading electrolyte

Details Liesegang patterns: Effect of dissociation of the invading electrolyte Liesegang patterns: Effect of dissociation of the invading electrolyte

1998-09-29

arxiv.org/abs/cond-mat/9809385v1

J. Phys. Chem. A 103, 1432 (1999)

Physics

Condensed Matter

Statistical Mechanics

RevTex, 8 pages, 3 eps figures

Scientific paper

The effect of dissociation of the invading electrolyte on the formation of Liesegang bands is investigated. We find, using organic compounds with known dissociation constants, that the spacing coefficient, 1+p, that characterizes the position of the n-th band as x_n ~ (1+p)^n, decreases with increasing dissociation constant, K_d. Theoretical arguments are developed to explain these experimental findings and to calculate explicitly the K_d dependence of 1+p.

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