Bethe-Peierls Approximation for Linear Monodisperse Polymers Re-examined

Details Bethe-Peierls Approximation for Linear Monodisperse Polymers Re-examined Bethe-Peierls Approximation for Linear Monodisperse Polymers Re-examined

2005-09-22

arxiv.org/abs/cond-mat/0509582v5

Physics

Condensed Matter

Statistical Mechanics

9 pages, 3 figures

Scientific paper

Bethe-Peierls approximation, as it applies to the thermodynamics of polymer melts, is reviewed. We compare the computed configurational entropy of monodisperse linear polymer melt with Monte Carlo data available in literature. An estimation of the configurational contribution to the total liquid's Cp is presented. We also discuss the relation between Kauzmann paradox and polymer semiflexibility.

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