Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2006-02-27
Phys. Rev. B 73, 121101(R) (2006)
Physics
Condensed Matter
Strongly Correlated Electrons
5 pages, 4 figures, accepted for publication in PRB
Scientific paper
10.1103/PhysRevB.73.121101
Thermoelectric properties of GdBaCo_{2}O_{5+x} and NdBaCo_{2}O_{5+x} single crystals have been studied upon continuous doping of CoO_2 planes with either electrons or holes. The thermoelectric response and the resistivity behavior reveal a hopping character of the transport in both compounds, providing the basis for understanding the recently found remarkable divergence of the Seebeck coefficient at x=0.5. The doping dependence of the thermoelectric power evinces that the configurational entropy of charge carriers, enhanced by their spin and orbital degeneracy, plays a key role in the origin of the large thermoelectric response in these correlated oxides.
Ando Yoichi
Lavrov Nicolay A.
Taskin Alexey A.
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