New mean field theories for the liquid-vapor transition of charged hard spheres

Details New mean field theories for the liquid-vapor transition of charged hard spheres New mean field theories for the liquid-vapor transition of charged hard spheres

2004-09-17

arxiv.org/abs/cond-mat/0409455v1

Mol. Phys. 103, 1271 (2005).

Physics

Condensed Matter

Statistical Mechanics

17 pages, 4 figures, 3 tables

Scientific paper

10.1080/00268970412331332105

The phase behavior of the primitive model of electrolytes is studied in the framework of various mean field approximations obtained recently by means of methods pertaining to statistical field theory (CAILLOL, J.-M., 2004, \textit{J. Stat. Phys.}, \textbf{115}, 1461). The role of the regularization of the Coulomb potential at short distances is discussed in details and the link with more traditional approximations of the theory of liquids is discussed. The values computed for the critical temperatures, chemical potentials, and densities are compared with available Monte Carlo data and other theoretical predictions.

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