Nonanalytical equation of state of the hard sphere fluid

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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5 pages, 3 figures

Scientific paper

10.1039/b511999e

An equation of state of the hard sphere fluid which is not analytical at the
freezing density is proposed and tested. The nonanalytical term is based on the
the classical nucleation theory and is able to capture the observed ``anomalous
increase'' of pressure at high densities. It is combined with the virial
expansion at low densities.

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