Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2001-02-12
Journal of Chemical Physics, v. 115, n. 1, pp. 567-574, 2001.
Physics
Condensed Matter
Soft Condensed Matter
10 pages, including 10 figures; a few typos are fixed, and several references added
Scientific paper
10.1063/1.1377033
We report molecular dynamics simulation of the (overall neutral) system consisting of an immobile macroion surrounded by the electrolyte of multivalent counterions and monovalent coions. As expected theoretically, counterions adsorb on the macroion surface in the amount much exceeding neutralization requirement, thus effectively inverting the sign of the macroion charge. We find two conditions necessary for charge inversion, namely, counterions must be multivalently charged and Coulomb interactions must be strong enough compared to thermal energy. On the other hand, coion condensation on the multivalent counterions similar to Bjerrum pairing is the major factor restricting the amount of charge inversion. Depending on parameters, we observe inverted charge up to about 200% the original charge of the macroion in absolute value. Our findings are consistent with the theory of "giant charge inversion" [Phys.Rev.Lett., v. 85, 1568 (2000)].
Grosberg Alexander
Tanaka Motohiko
No associations
LandOfFree
Giant Charge Inversion of a Macroion Due to Multivalent Counterions and Monovalent Coions: Molecular Dynamics Study does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Giant Charge Inversion of a Macroion Due to Multivalent Counterions and Monovalent Coions: Molecular Dynamics Study, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Giant Charge Inversion of a Macroion Due to Multivalent Counterions and Monovalent Coions: Molecular Dynamics Study will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-444034