Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2009-09-10
Physics
Condensed Matter
Soft Condensed Matter
12 pages, 1 figure
Scientific paper
The spreading of a circular liquid drop on a solid substrate can be described by the time evolution of its base radius R(t). In complete wetting the quasistationary regime (far away from initial and final transients) typically obeys the so-called Tanner law, with R t^alpha_T, alpha_T=1/10. Late-time spreading may differ significantly from the Tanner law: in some cases the drop does not thin down to a molecular film and instead reaches an equilibrium pancake-like shape; in other situations, as revealed by recent experiments with spontaneously spreading nematic crystals, the growth of the base radius accelerates after the Tanner stage. Here we demonstrate that these two seemingly conflicting trends can be reconciled within a suitably revisited energy balance approach, by taking into account the line tension contribution to the driving force of spreading: a positive line tension is responsible for the formation of pancake-like structures, whereas a negative line tension tends to lengthen the contact line and induces an accelerated spreading (a transition to a faster power law for R(t) than in the Tanner stage).
Cazabat Anne-Marie
Mechkov Serguei
Oshanin Gleb
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