Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2002-01-28
Physics
Condensed Matter
Statistical Mechanics
10 pages, 3 figures, to be published in Physical Review E
Scientific paper
10.1103/PhysRevE.65.046124
Estimating the probability distribution 'q' governing the behaviour of a certain variable by sampling its value a finite number of times most typically involves an error. Successive measurements allow the construction of a histogram, or frequency count 'f', of each of the possible outcomes. In this work, the probability that the true distribution be 'q', given that the frequency count 'f' was sampled, is studied. Such a probability may be written as a Gibbs distribution. A thermodynamic potential, which allows an easy evaluation of the mean Kullback-Leibler divergence between the true and measured distribution, is defined. For a large number of samples, the expectation value of any function of 'q' is expanded in powers of the inverse number of samples. As an example, the moments, the entropy and the mutual information are analyzed.
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