Viscous Flow and Jump Dynamics in Molecular Supercooled Liquids: II Rotations

Details Viscous Flow and Jump Dynamics in Molecular Supercooled Liquids: II Rotations Viscous Flow and Jump Dynamics in Molecular Supercooled Liquids: II Rotations

1999-12-10

arxiv.org/abs/cond-mat/9912183v1

Physics

Condensed Matter

Statistical Mechanics

12 pages, 13 figures, submitted to Phys.Rev.E

Scientific paper

The rotational dynamics of a supercooled molecular liquid is investigated by
a molecular-dynamics numerical study. We detect rotational jumps with a
waiting-time distribution which is well fitted by a truncated power law. At
lower temperatures the rotational correlation times are decoupled from the
viscosity.

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