Synthesis and Structure of the Monolayer Hydrate K03CoO2 x 04H2O

Details Synthesis and Structure of the Monolayer Hydrate K03CoO2 x 04H2O Synthesis and Structure of the Monolayer Hydrate K03CoO2 x 04H2O

2005-03-07

arxiv.org/abs/cond-mat/0503165v1

Physics

Condensed Matter

Materials Science

11 pages, 5 figures, 1 table, to be published in Solid State Communications

Scientific paper

10.1016/j.ssc.2005.03.007

The monolayer hydrate (MLH) K03CoO2 x 04H2O was synthesized from K06CoO2 by extracting K+ cations using K2S2O8 as an oxidant and the subsequent intercalation of water between the layers of edge-sharing CoO6 octahedra. A hexagonal structure (space group P63/mmc) with lattice parameters a = 2.8262(1) Angstrom, c = 13.8269(6) Angstrom similar to the MLH Na036CoO2 x 07H2O was established using high-resolution synchrotron X-ray powder diffraction data. The K/H2O layer in the K-MLH is disordered, which is in contrast to the Na-MLH. At low temperatures metallic and paramagnetic behavior was found.

Affiliated with

Also associated with

No associations

Rating

Synthesis and Structure of the Monolayer Hydrate K03CoO2 x 04H2O does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Synthesis and Structure of the Monolayer Hydrate K03CoO2 x 04H2O, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Synthesis and Structure of the Monolayer Hydrate K03CoO2 x 04H2O will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-403023