Structure factor and thermodynamics of rigid dendrimers in solution

Details Structure factor and thermodynamics of rigid dendrimers in solution Structure factor and thermodynamics of rigid dendrimers in solution

2007-05-23

arxiv.org/abs/0705.3331v1

Physics

Condensed Matter

Soft Condensed Matter

7 pages, 5 figures, submitted

Scientific paper

10.1063/1.2750339

The ''polymer reference interaction site model'' (PRISM) integral equation theory is used to determine the structure factor of rigid dendrimers in solution. The theory is quite successful in reproducing experimental structure factors for various dendrimer concentrations. In addition, the structure factor at vanishing scattering vector is calculated via the compressibility equation using scaled particle theory and fundamental measure theory. The results as predicted by both theories are systematically smaller than the experimental and PRISM data for platelike dendrimers.

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