Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2007-07-20
Physics
Condensed Matter
Statistical Mechanics
Small corrections and revisions throughout the text, several references together with discussion with relation to the present
Scientific paper
We present the perturbative solution of the multicomponent Boltzmann kinetic equation based on the set of observables including the hydrodynamic velocity and temperature for each component. The solution is obtained by modifying the formal density scaling scheme by Enskog, such that the density of each component is scaled independently. As a result we obtain the species momentum and energy balance equations with the source terms describing the transfer of corresponding quantities between different components. In the zero order approximation those are the Euler equations with the momentum and heat diffusion included in the form of the classical Maxwell-Stefan diffusion terms. The first order approximation results in equations of a Navier-Stokes type with the partial viscosity and heat conductivity including only the correlations of the particles of the same component. The first order corrections to the Maxwell-Stefan terms as well as the contributions bilinear in gradients and differences of observables are calculated. The first order momentum source term is shown to include thermal diffusion. The nondiagonal (in component indexes) components of viscosity and heat conductivity appear as second order contributions.
Kerkhof J. A. P. M.
Peters A. J. E. F.
Savenko S. V.
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