Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2002-05-27
Physics
Condensed Matter
Statistical Mechanics
10 pages, 3 figures
Scientific paper
The impossibility of separating into work and heat the energy transmitted between two subsystems through a movable piston is analyzed in this article. The process here described, although "quasi-static", is not reversible. It is shown that the First Principle, dU=dW+dQ, introduced by Clausius, does not generally allow a physical identification of dW and dQ, although dU=-pdV+TdS is verified along the equilibrium points of each subsystem.
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