Spin Frustration and Magnetic Exchange in Cobalt Aluminum Oxide Spinels

Physics – Condensed Matter – Materials Science

Scientific paper

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19 pages, 9 figures, 46 references

Scientific paper

10.1103/PhysRevB.77.094412

We report on x-ray diffraction, magnetic susceptibility, electron- spin resonance and heat- capacity studies of Co[Al_1-xCo_x]_2O_4 for Co concentrations 0 10 indicates the presence of strong spin frustration at least for x < 0.6. The frustration mechanism is attributed to competing nearest neighbor and next-nearest neighbor superexchange interactions between the A-site Co^2+ ions.

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