Structure of Extremely Nanosized and Confined In-O Species in Ordered Porous Materials

Physics – Condensed Matter – Materials Science

Scientific paper

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4 pages, 5 postscript figures, REVTEX4, published in Physical Review Letters

Scientific paper

10.1103/PhysRevLett.91.108304

Perturbed-angular correlation, x-ray absorption, and small-angle x-ray scattering spectroscopies were suitably combined to elucidate the local structure of highly diluted and dispersed InOx species confined in porous of ZSM5 zeolite. These novel approach allow us to determined the structure of extremely nanosized In-O species exchanged inside the 10-atom-ring channel of the zeolite, and to quantify the amount of In2O3 crystallites deposited onto the external zeolite surface.

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