Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2004-07-13
J. Stat. Mech: Theor. Exp. P09005 (2004)
Physics
Condensed Matter
Statistical Mechanics
16 pages, no figures, added appendix; published in J.Stat.Mech: Theor.Exp. as "Nonequilibrium work theorem for a system strong
Scientific paper
In a recent paper [ J. Stat. Mech. P07006 (2004)], E.G.D. Cohen and David Mauzerall (CM) have argued that the derivation of the nonequilibrium work relation given in [C. Jarzynski, Phys. Rev. Lett. 78, 2690 (1997)] is flawed. Here I attempt to answer their criticisms, both by presenting a detailed version of that derivation and by addressing specific objections raised by CM. The derivation presented here is in fact somewhat stronger than the one I gave in 1997, as it does not rely on the assumption of a weak coupling term between the system of interest and its thermal environment.
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