Charge inversion in colloidal systems

Details Charge inversion in colloidal systems Charge inversion in colloidal systems

2002-01-08

arxiv.org/abs/cond-mat/0201111v1

Physics

Condensed Matter

Soft Condensed Matter

6 pages, LATEX (elsevier), 4 EPS files - Proceedings of CCP 2001 (Conference on Computational Physics 2001, Aachen, Germany 5-

Scientific paper

10.1016/S0010-4655(02)00288-6

We investigate spherical macroions in the strong Coulomb coupling regime within the primitive model in salt-free environment. Molecular dynamics (MD) simulations are used to elucidate the effect of $discrete$ macroion charge distribution on charge inversion. A systematic comparison is made with the charge inversion obtained in the conventional continuous charge distribution. Furthermore the effect of multivalent counterions is reported.

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