The Synthesis and Characterization of LiFeAs and NaFeAs

Details The Synthesis and Characterization of LiFeAs and NaFeAs The Synthesis and Characterization of LiFeAs and NaFeAs

2009-02-04

arxiv.org/abs/0902.0806v1

Physics

Condensed Matter

Superconductivity

submitted for publication in Physica C special issue on Fe-pnictides

Scientific paper

The newest homologous series of superconducting As-pnictides, LiFeAs (Li111) and NaFeAs (Na111) have been synthesized and investigated. Both crystallize with the layered tetragonal anti-PbFCl-type structure in P4/nmm space group. Polycrystalline samples and single-crystals of Li111 and Na111 display superconducting transitions at ~ 18 K and 12-25 K, respectively. No magnetic order has been found in either compound, although a weak magnetic background is clearly in evidence. The origin of the carriers and the stoichiometric compositions of Li111 and Na111 were explored.

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