Fractionation of polydisperse systems: multi-phase coexistence

Details Fractionation of polydisperse systems: multi-phase coexistence Fractionation of polydisperse systems: multi-phase coexistence

1999-01-26

arxiv.org/abs/cond-mat/9901283v1

Physics

Condensed Matter

Statistical Mechanics

4 pages, 1 figure

Scientific paper

10.1103/PhysRevE.59.3192

The width of the distribution of species in a polydisperse system is employed in a small-variable expansion, to obtain a well-controlled and compact scheme by which to calculate phase equilibria in multi-phase systems. General and universal relations are derived, which determine the partitioning of the fluid components among the phases. The analysis applies to mixtures of arbitrarily many slightly-polydisperse components. An explicit solution is approximated for hard spheres.

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