Pressure induced high-spin to low-spin transition in FeS evidenced by x-ray emission spectroscopy

Details Pressure induced high-spin to low-spin transition in FeS evidenced by x-ray emission spectroscopy Pressure induced high-spin to low-spin transition in FeS evidenced by x-ray emission spectroscopy

1998-06-19

arxiv.org/abs/cond-mat/9806245v3

Physics

Condensed Matter

Materials Science

ReVTeX, 4 pages, 3 figures inserted with epsfig. minor modifications before submission to PRL

Scientific paper

10.1103/PhysRevLett.82.3284

We report the observation of the pressure-induced high-spin to low-spin transition in FeS using new high-pressure synchrotron x-ray emission spectroscopy techniques. The transition is evidenced by the disappearance of the low-energy satellite in the Fe K$\beta$ emission spectrum of FeS. Moreover, the phase transition is reversible and closely related to the structural phase transition from a manganese phosphide-like phase to a monoclinic phase. The study opens new opportunities for investigating the electronic properties of materials under pressure.

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