Virial Equation-of-State for Hard Spheres

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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Hard-sphere fluid: 4 pages 2 tables 2 figures

Scientific paper

Recent values for virial coefficients up to B12, when expressed in powers of density relative to maximum close packing,lead to a closed equation-of-state for the equilibrium fluid. The series obtained converges for all densities;it becomes negative and diverges to a negative pole at maximum packing. MD data for 64000 spheres in the metastable region shows the virial pressure begins to deviate at the fluid freezing density.

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