Driven Diffusion in Periodic Potentials with Stochastic Path Integral Hyperdynamics

Details Driven Diffusion in Periodic Potentials with Stochastic Path Integral Hyperdynamics Driven Diffusion in Periodic Potentials with Stochastic Path Integral Hyperdynamics

2009-06-02

arxiv.org/abs/0906.0607v1

Physics

Condensed Matter

Statistical Mechanics

5 pages, 3 figures

Scientific paper

We consider the driven diffusion of Brownian particles in 1D periodic potentials using the recently proposed Stochastic Path Integral Hyperdynamics (SPHD) scheme [L.Y. Chen and L.J.M. Horing, J. Chem. Phys. {\bf 126}, 224103 (2007)]. First, we consider the case where a single Brownian particle is moving in a spatially periodic potential and subjected to an external ac driving force. We confirm that there is no stochastic resonance in this system and find that at higher frequencies the diffusion coefficient $D$ is strongly suppressed. The second case is that of a dimer moving in a periodic potential with a static bias. For this case, there's a strong suppression of $D$ when the dimer bond length is an integer multiple of the lattice constant of the potential. For both cases, we demonstrate how the SPHD allows us to extract the dynamical information exactly at different bias levels from a single simulation run, by calculating the corresponding statistical re-weighting factors.

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