Correlation-dependent coherent to incoherent transitions in resonant energy transfer dynamics

Physics – Condensed Matter – Mesoscale and Nanoscale Physics

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5 pages, 1 figure, 2 page supplement. Published version. Figure edited, section added on experimental relevance, reference add

Scientific paper

10.1103/PhysRevLett.103.146404

I investigate energy transfer in a donor-acceptor pair beyond weak system-bath coupling. I identify a transition from coherent to incoherent dynamics with increasing temperature, due to multi-phonon effects not captured by a standard weak-coupling treatment. The crossover temperature has a marked dependence on the degree of spatial correlation between fluctuations experienced at the two system sites. For strong correlations, this leads to the possibility of coherence surviving into a high temperature regime.

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