Mesoscopic simulations of polyelectrolyte electrophoresis in nanochannels

Details Mesoscopic simulations of polyelectrolyte electrophoresis in nanochannels Mesoscopic simulations of polyelectrolyte electrophoresis in nanochannels

2010-07-21

arxiv.org/abs/1007.3585v1

Physics

Condensed Matter

Soft Condensed Matter

15 pages, 6 figures

Scientific paper

We present the results of mesoscopic dissipative particle dynamics (DPD) simulations of coupled electrohydrodynamic phenomena on the micro- and nanoscale. The effects of electroosmotic flow and slippage combined with polyelectrolyte electrophoresis are investigated in detail, taking full account of hydrodynamic and electrostatic interactions. Our numerical results are in excellent agreement with analytical calculations.

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