Topological defects and shape of aromatic self-assembled vesicles

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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accepted as a Letter in the J. Phys. Chem. B

Scientific paper

10.1021/jp904300a

We show that the stacking of flat aromatic molecules on a curved surface
results in topological defects. We consider, as an example, spherical vesicles,
self-assembled from molecules with 5- and 6-thiophene cores. We predict that
the symmetry of the molecules influences the number of topological defects and
the resulting equilibrium shape.

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