Thermal Effects in Photoemission and Electron-Phonon Couplings of Fullerene

Details Thermal Effects in Photoemission and Electron-Phonon Couplings of Fullerene Thermal Effects in Photoemission and Electron-Phonon Couplings of Fullerene

2004-07-06

arxiv.org/abs/cond-mat/0407132v1

Fullerenes and Nanotubes - Materials for the New Chemical Frontier - Fullerenes - Vol. 14, edited by P. V. Kamat, F. D'Souza,

Physics

Condensed Matter

Materials Science

Proceedings of the fullerene symposia of the 205rd Meeting of The Electrochemical Society San Antonio, TX, USA, May 9 - 13, 20

Scientific paper

We show that thermal effects play a relevant role in the determination of the electron-phonon couplings based on the intensity of the phonon-shakeup peaks in photoemission spectra. In particular, we re-consider the determination of the electron-phonon couplings of fullerene based on a fit of the photoemission spectrum of C60- in gas phase [Gunnarsson PRB 1995]. We show that taking thermal effects into account reduces the obtained couplings by approximately 10%.

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