The effect of particle size polydispersity on freezing of hard spheres

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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Colloids, Order-Disorder Transformations, Statistical Mechanics Of Model Systems, Density-Functional Theory

Scientific paper

A density functional theory of non-uniform fluid is applied to an
investigation of the freezing of size polydisperse hard-sphere system.
It was found that there is some critical standard deviation of the size
distribution divided by the mean size above which no crystallization
takes place for arbitrary density. .

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