Local dielectric permittivity near an interface

Details Local dielectric permittivity near an interface Local dielectric permittivity near an interface

2003-04-02

arxiv.org/abs/cond-mat/0304062v1

Europhys. Lett. 63 (2003): 381-387

Physics

Condensed Matter

Statistical Mechanics

7 pages

Scientific paper

10.1209/epl/i2003-00464-8

A statistical mechanics expression is derived for the space-dependent dielectric permittivity of a polar solvent near an interface. The asymptotic behaviour of this local permittivity is calculated in the low density limit, near a planar interface. The potential of mean force between two ions is shown to agree with the prediction of macroscopic electrostatics for large separations parallel to the interface.

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