Phase behavior of the Lattice Restricted Primitive Model with nearest-neighbor exclusion

Details Phase behavior of the Lattice Restricted Primitive Model with nearest-neighbor exclusion Phase behavior of the Lattice Restricted Primitive Model with nearest-neighbor exclusion

2006-03-03

arxiv.org/abs/cond-mat/0603077v1

Physics

Condensed Matter

Soft Condensed Matter

6 pages, color. submitted to J. Chem. Phys

Scientific paper

10.1063/1.2192498

The global phase behavior of the lattice restricted primitive model with nearest neighbor exclusion has been studied by grand canonical Monte Carlo simulations. The phase diagram is dominated by a fluid (or charge-disordered solid) to charge-ordered solid transition that terminates at the maximum density, $\rho^*_{max}=\sqrt2$ and reduced temperature $T^*\approx0.29$. At that point, there is a first-order phase transition between two phases of the same density, one charge-ordered and the other charge-disordered. The liquid-vapor transition for the model is metastable, lying entirely within the fluid-solid phase envelope.

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