Measurements of the electronic transition moments of C2-band systems

Physics

Scientific paper

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Carbon, Electron Transitions, Fine Structure, Infrared Spectra, Molecular Spectra, Gas Mixtures, Gas Spectroscopy, Incident Radiation, Infrared Radiometers, Shock Heating, Shock Tubes, Spectral Line Width

Scientific paper

Electronic transition moments of seven C2 singlet and triplet band systems, which are in the 0.2 to 1.2 micron spectral region, have been measured. The measurements were made in emission behind incident shock waves in C2H2-argon mixtures. Narrow band-pass radiometers were used to obtain absolute measurements of shock-excited C2 radiation from which absolute electronic transition moments are derived by a synthetic spectrum analysis. New results are reported for the Ballik-Ramsay, Phillips, Swan, Deslandres-d'Azambuja, Fox-Herzberg, Mulliken, and Freymark systems.

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