Soft x-ray magnetic circular dichroism on a paramagnetic bioinorganic system

Details Soft x-ray magnetic circular dichroism on a paramagnetic bioinorganic system Soft x-ray magnetic circular dichroism on a paramagnetic bioinorganic system

Feb 1994

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1994spie.2010..181v&link_type=abstract

Proc. SPIE Vol. 2010, p. 181-189, X-Ray and Ultraviolet Polarimetry, Silvano Fineschi; Ed.

Physics

1

Scientific paper

In this paper we report soft X-ray Magnetic Circular Dichroism experiments on paramagnetic bioinorganic systems. We measured the Fe L-edges and the Co L-edges of the Co substituted form of Pyrococcus furiosus rubredoxin, using circularly polarized synchrotron radiation, a split coil superconducting magnet, low sample temperatures, and fluorescence detection. The observed dichroism effects are strong and they can be interpreted by established theoretical procedures. Soft X-ray Magnetic Circular Dichroism demonstrates enormous potential as a new probe for studying paramagnetic bioinorganic systems.

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