Electrochemistry of reduced sulfur species in natural waters--I. The H 2 S-H 2 O system

Details Electrochemistry of reduced sulfur species in natural waters--I. The H 2 S-H 2 O system Electrochemistry of reduced sulfur species in natural waters--I. The H 2 S-H 2 O system

Sep 1978

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1978gecoa..42.1439b&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 42, Issue 9, pp.1439-1445

Physics

Scientific paper

Careful measurements of rest potentials of platinum electrodes (Eh) in the H 2 S-H 2 O system were made together with measurements of the pH and the potentials of Ag-Ag 2 S electrodes (E s 2- ). The potentials of the platinum electrode are characteristic of H 2 S chemisorption followed by H 2 S discharge on the platinum. The relations between Eh, E s 2- and pH are characteristic of the H 2 S-H 2 O system and of the hydrogen sulfide concentration. Thus these parameters can be employed to distinguish H 2 S-H 2 O systems from H 2 S-S 8 -H 2 O systems. Field measurements on hot sulfurous springs are in agreement with laboratory data.

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