Absorption cross sections of some atmospheric molecules for resonantly scattered O I 1304-A radiation

Physics

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Absorption Cross Sections, Atmospheric Composition, Molecular Absorption, Oxygen Atoms, Oxygen Spectra, Resonance Scattering, Carbon Monoxide, Line Spectra, Methane, Nitrogen, Nitrous Oxides, Pressure Effects

Scientific paper

Absorption cross sections for O2, N2, CO2, CH4, N2O, and CO have been measured at each of the lines of the atomic oxygen triplet at 1302, 1305, and 1306 A. Radiation resonantly scattered from oxygen atoms at a temperature of about 300 K was used for the line source. Absorber temperatures were also near 300 K. Direct application of the Lambert-Beer absorption equation yielded pressure-dependent cross sections for carbon monoxide at each line of the O I triplet. Reasons for this apparent dependence are presented and discussed.

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