On the complex magnetic behaviour of titanomagnetites

Physics

Scientific paper

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Scientific paper

The bulk magnetic properties, including Curie temperature, susceptibility and hysteresis at various temperatures, and the Mössbauer spectra of coarse synthetic members of the titanomagnetite series are compared as a function of titanium content, using some previously reported and some new results. It has been noted previously that the titanium-rich members fail to show the expected ``true multidomain'' behaviour observed in pure magnetite. One possible explanation is that the behaviour observed may be due to a tendency to inhibit domain wall formation in some titanomagnetites. In this paper we discuss some other possible mechanisms to account for the magnetic properties of such titanomagnetites observable even when domain-wall-related structures do form in them. These mechanisms suggest that magnetocrystalline anisotropy and its temperature dependence in titanomagnetites may be related to local magnetic inhomogeneities, and do not depend only on crystal structure as in the case of classical ferromagnetic materials.

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