Nonstoichiometry effect on mercury thiogallate luminescence

Details Nonstoichiometry effect on mercury thiogallate luminescence Nonstoichiometry effect on mercury thiogallate luminescence

Sep 1991

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1991spie.1512..204y&link_type=abstract

Proc. SPIE Vol. 1512, p. 204-212, Infrared and Optoelectronic Materials and Devices, Ahmed Naumaan; Carlo Corsi; Joseph M. Baixe

Physics

Scientific paper

Deviation from stoichiometry to Ga2S3 excess is shown to be an effective method to obtain mercury thiogallate crystals with strong 670 nm luminescence, photosensitivity at (lambda) < 700 nm and large light-sums storage. The smaller Ga cations are able to create easier antistructural Ga(mu g) defects, to occupy stoichiometric voids, and interstitial sites are supposed to be responsible for the changes.

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