Spin splitting in the Chi Sigma-2/+/ state of MgH

Details Spin splitting in the Chi Sigma-2/+/ state of MgH Spin splitting in the Chi Sigma-2/+/ state of MgH

Apr 1982

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1982jchph..76.3692c&link_type=abstract

Journal of Chemical Physics, vol. 76, Apr. 1, 1982, p. 3692, 3693.

Physics

Chemical Physics

2

Electron Spin, Magnesium Compounds, Metal Hydrides, Molecular Spectroscopy, Perturbation Theory, Angular Momentum, Electron States, Hyperfine Structure, Interstellar Matter, Molecular Energy Levels, Quantum Theory, Wave Functions

Scientific paper

The spin splitting constant for the Chi Sigma-2(+) state of MgH is calculated using second-order perturbation theory and ab initio wave functions. The constant is found to be 0.019/cm, and it is noted that further small splittings will arise from nuclear hyperfine interactions. The nature of the spin splitting constant is considered, and a comparison is made with the Lambda-doubling parameter, which demonstrates a difference explicable in terms of the differences between the potential curves of the interacting states.

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