Photodissociation of Cl2O2 in the spring Antarctic lower stratosphere

Details Photodissociation of Cl2O2 in the spring Antarctic lower stratosphere Photodissociation of Cl2O2 in the spring Antarctic lower stratosphere

May 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990georl..17..721e&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 17, May 1990, p. 721-724.

Physics

6

Antarctic Regions, Chlorine Oxides, Photodissociation, Spring (Season), Stratosphere, Absorption Cross Sections, Absorption Spectra, Dimers, Light (Visible Radiation)

Scientific paper

The likely photodissociation pathways of chlorine peroxide are examined. Reasoning by analogy between hydrogen peroxide and chlorine peroxide, it is shown that photodissociation of chlorine peroxide at wavelengths longer than 250 nm is not likely to give chlorine atoms as a primary product. Reasoning by analogy with molecules whose visible spectra are known, it is concluded that chlorine peroxide is also likely to photodissociate in the visible to give ClO radicals as primary products.

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