Rotational spectrum and equilibrium structure of silanethione, H2Si=S

Physics

Scientific paper

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Scientific paper

Unsubstituted silanethione, H2Si=S, has been characterized
experimentally for the first time by means of rotational spectroscopy;
the equilibrium structure of this fundamental molecule has been
evaluated through a combination of experimental data from a total of ten
isotopologues and results of high-level coupled-cluster calculations.

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