Rotational spectrum of HD at low pressures

Details Rotational spectrum of HD at low pressures Rotational spectrum of HD at low pressures

Dec 1984

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1984cajph..62.1680e&link_type=abstract

Canadian Journal of Physics (ISSN 0008-4204), vol. 62, Dec. 1984, p. 1680-1685. Research supported by the Max-Planck-Institut fü

Physics

19

Absorption Spectra, Deuterides, Hydrogen Compounds, Rotational Spectra, Dipole Moments, Electric Dipoles, Laser Spectroscopy, Line Spectra, Molecular Spectra, Spectral Line Width

Scientific paper

The frequencies of three pure rotational transitions of HD gas, R(3), R(5), and R(6), have been measured at low pressure, permitting improved values for the rotational constants to be estimated. Line widths, strengths, and transition moments have also been determined. The values of the dipole moment derived from the intensities are 8.47 + or - 0.09 x 10 to the -4th, 8.1 + or - 0.8 x 10 to the -4th, and 9.9 + or - 0.3 x 10 to the -4th D for the three lines, respectively. A line-narrowing effect was observed that permitted an estimate of the self-diffusion coefficient.

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