Manipulating the torsion of molecules by strong laser pulses

Physics – Atomic Physics

Scientific paper

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4 pages, 4 figures, submitted to PRL; Major revision of the presentation of the material; Correction of ion labels in Fig. 2(a

Scientific paper

10.1103/PhysRevLett.102.073007

A proof-of-principle experiment is reported, where torsional motion of a molecule, consisting of a pair of phenyl rings, is induced by strong laser pulses. A nanosecond laser pulse spatially aligns the carbon-carbon bond axis, connecting the two phenyl rings, allowing a perpendicularly polarized, intense femtosecond pulse to initiate torsional motion accompanied by an overall rotation about the fixed axis. The induced motion is monitored by femtosecond time-resolved Coulomb explosion imaging. Our theoretical analysis accounts for and generalizes the experimental findings.

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