Spectrum Generating Algebra for X$_{3}$ Molecules

Details Spectrum Generating Algebra for X$_{3}$ Molecules Spectrum Generating Algebra for X$_{3}$ Molecules

1995-07-06

arxiv.org/abs/chem-ph/9507002v1

Phys. Rev. A52 (1995) 2786

Physics

Chemical Physics

15 pages, to appear in Physical Review A

Scientific paper

10.1103/PhysRevA.52.2786

A new spectrum generating algebra for a unified description of rotations and
vibrations in polyatomic molecules is introduced. An application to nonlinear
X$_3$ molecules shows that this model (i) incorporates exactly the relevant
point group, (ii) provides a complete classification of oblate top states, and
(iii) treats properly both degenerate and nondegenerate vibrations.

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