Reaction of C_2(a^3Pi_u) with methanol: Temperature dependence and deuterium isotope effect

Details Reaction of C_2(a^3Pi_u) with methanol: Temperature dependence and deuterium isotope effect Reaction of C_2(a^3Pi_u) with methanol: Temperature dependence and deuterium isotope effect

2010-02-05

arxiv.org/abs/1002.1203v4

J. Chem. Phys. 133, 114306 (2010)

Physics

Chemical Physics

27 pages, 6 figures, 3 tables, 54 references; accepted to JCP

Scientific paper

We present a first temperature dependence and kinetic isotope effect study on the reaction of C_2(a^3Pi_u) with methanol. The bimolecular rate constants for a series of methanol isotopomers have been measured as a function of temperature between 293 and 673 K. The observed positive temperature dependences as well as deuterium kinetic isotope effects permit determination of the reaction mechanism as a site-specific hydrogen abstraction from the methyl site rather than from the hydroxyl site.

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