Long-range interactions for He($n S$)--He$(n' S)$ and He($n S$)--He$(n' P)$

Physics – Atomic Physics

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Scientific paper

10.1103/PhysRevA.74.014704

The energetically lowest five states of a helium atom are: He($1^1S$),
He($2^3S$), He($2^1S$), He($2^3P$), and He($2^1P$). Long-range interaction
coefficients $C_3$, $C_6$, $C_8$, $C_9$, and $C_{10}$ for all $S-S$ and $S-P$
pairs of these states are calculated precisely using correlated wave functions
in Hylleraas coordinates. Finite nuclear isotope mass effects are included.

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