Physics – Quantum Physics
Scientific paper
2003-05-26
Journal of Chemical Physics 120 (2004) 1318
Physics
Quantum Physics
This article is part of Daniel Comparat's PhD thesis available at http://tel.ccsd.cnrs.fr/
Scientific paper
10.1063/1.1626539
NDE (Near-dissociation expansion) including LeRoy-Bernstein formulas are improved by taking into account the multipole expansion coefficients and the non asymptotic part of the potential curve. Applying these new simple analytical formulas to photoassociation spectra of cold alkali atoms, we improve the determination of the asymptotic coefficient, reaching a 1% accuracy, for long-range relativistic potential curve of diatomic molecules.
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