Electric dipole rovibrational transitions in HD molecule

Details Electric dipole rovibrational transitions in HD molecule Electric dipole rovibrational transitions in HD molecule

2008-09-22

arxiv.org/abs/0809.3736v1

Physics

Chemical Physics

7 pages, 1 figure

Scientific paper

10.1103/PhysRevA.78.052503

The rovibrational electric dipole transitions in the ground electronic state of the HD molecule are studied. A simple, yet rigorous formula is derived for the transition rates in terms of the electric dipole moment function $D(R)$, which is calculated in a wide range of $R$. Our numerical results for transition rates are in moderate agreement with experiments and previous calculations, but are at least an order of magnitude more accurate.

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